Friday, November 15, 2013

A comparison between the Enthalpy of formation of MgO acquired via a series of reactions and Hess's Law (will they be equivalent?)

Enthalpy of FormationBackgroundThe total enkindle of system (ΔH°f) is be as the rouse change associated with the make-up of one gram molecule of a commingle from its elements in their standard states. The major obstructor here, though, is that it is very unvoiced to measure most enthalpies of formations in a standard lab due to the amount of heat or toxic products that argon formed. Thus, in invest to acquire the desired results, one essential use Hess?s Law in which the henry of a series of reactions are measured and added in concert to fracture the utmost answer of the enthalpy of formation. In this situation, to follow the enthalpy of formation for MgO is very difficult in the testing ground (Mg(s) + ½ O2 (g) MgO(s)). But, through with(predicate) a series of reactions and Hess?s Law, the determination of the enthalpy of formation is make possible. Thus, in this investigation, we provide see how stainless and precise Hess?s Law can be. MgO(s) + 2 H +(aq) Mg2+(aq) + H2O(l) ΔH°2 = ?Mg(s) + 2 H+(aq) Mg2+(aq) + H2(g) ΔH°3 = ?+H2(g) + ½ O2(g) H2O(l) ΔH°4 = ?286 kJ/molMg(s) + ½ O2 (g) MgO(s) ΔH°f = ?The series of reactions that will be use and whose enthalpies will be combined to give the enthalpy of formation of MgO are listed above. The setoff shade, though, has MgO in the reactant rouse outment, but in the equality above that, MgO is supposed to be in the product side (enthalpy of formation). Thus, the sign for the enthalpy of the first reaction must be switched; if it?s positive, then it becomes controvert and vice versa. Hypothesis:If a series of reactions are apply to determine the ΔH°f of MgO, then the experimental quantify acquired in this investigation should be very close to the pass judgment value due to Hess?s Law. Variables:Independent Variables:The Molarity of the harsh usedThe type and amount of the elements usedDependent Variables:The enthalpy of formation of the MgOC ontrol of Variables:Several reactions that ! check been careful constructed are performed to a lower place fussy conditions to acquire the desired results. Materials and MethodMaterials200ml of 3.
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0M HClGraduated CylinderMagnesium StripsThermometerStyrofoam Cup w/LidWeighing ScaleMgO powderMethod and Procedure purpose 1: MgO(s) + 2 H+(aq) Mg2+(aq) + H2O(l)1.Take the Styrofoam instill and put 100 ml of 3.0 M HCl in it. 2.Weigh out about one thou of powder MgO. 3.Make a very small hole in the chapeau of the Styrofoam cup just big enough for the thermometer to fill through so no heat escapes. 4.Record the initial temperature of the HCl5.Then, place the MgO i nto the cup and quickly place the lid on it to counteract the heat from escaping6.Pick up the cup and stir it and record the largest temperature reached by the reaction. fall apart 2: Mg(s) + 2 H+(aq) Mg2+(aq) + H2(g)1.Repeat every step from Part 1 except use about 0.5 g of Mg metal (strips) instead of the MgO and record the initial and lowest temperatures in the cup. If you want to get a full essay, order it on our website: BestEssayCheap.com

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